Here is my argument:
”…what is “natural” is perceptible and all causes are natural causes.”
Materialism arose at a time when atomism dominated the common thinking. Even when physics moved beyond such simple models, the concept of one billiard ball striking another and setting it into motion ruled the common mentality from the early 18th Century until well into the 19th Century.
A thing’s “nature” is identified in terms of observable phenomena. It is the nature of a horse to gallop, of a ship to sail, and of a man to think. Any perceptible phenomena will do as nature—but it is impossible to identify a thing by a nature that hasn’t yet been perceived.
Causation is the movement from the phenomena of “cause” to the phenomena of “effect.” In his essay concerning Human Understanding, David Hume assured us that what is a matter of “a matter of fact” is not exempt from also being a matter of inferring from “our memories and senses”:
“If you were to ask a man, why he believes any matter of fact, which is absent, (for instance, that his friend is in the country, or in France) he would give you a reason, and this reason would be some other fact, as a letter received from him, or the knowledge of his former resolutions and promises. A man finding a watch or any other machine in a desert island, would conclude that there had once been men on that island. All our reasonings concerning fact are of the same nature. And here it is constantly supposed that there is a connection between the present fact and that which is inferred from it. Were there nothing to bind them together, the inference would be entirely precarious. The hearing of an articulate voice and rational discourse in the dark assures us of the presence of some person. Why? Because these are the effects of the human make and fabric, and closely connected with it. If we anatomise all the other reasonings of this nature, we shall find that they are founded on the relation of cause and effect, and that this relation is either near or remote, direct or collateral. Heat and light are collateral effects of fire, and the one effect may justly be inferred from the other.”
Natural materialism, a monism that discounts anything except nature and matter, stems from the idea that things beyond phenomena, things not accountable, do not fit into a comprehensive worldview.
On billiard balls, and other topics: Hume against the Mechanists:
http://www.richmond-philosophy.net/rjp/back_issues/rjp3_hill.pdf
On Cause and Effect, and Human Understanding:
https://www.marxists.org/reference/subject/philosophy/works/en/hume.htm