Because "what it is like to be an electron" remains a coherent question even after we know every property of the electron as they pertain to the electron's interactions with the rest of the universe. How X relates to every thing else is determinable, but how X relates to X itself is indeterminable as any investigation you do reveals only something about that entity X interacting with something other than itself.
Hmmm...I'm not so sure it *is* a coherent question. What sort of answer could it possibly have?
So, we can determine what it is like to be another person by studying our own brains and how we feel internally and then noting when someone else's brain has the same internal states, etc. We can collect evidence of how they report their internal states in various situations and compare what they report to what is happening in brain scans. We don't even have to believe their reports are accurate: just that they are reports and can be correlated with brain scans is enough to make progress.
This can be extended, at least to some extent with many other types of brains (finding the types of information they process, etc).
But I'm not sure it is a coherent question to ask what it is like to be an electron: it simply doesn't have the structure required to have an internal state described by a 'what is it like?' answer. From everything I can see, consciousness is a particular type of information processing. Anything without that information processing would then not have consciousness and no 'internal state' in the sense of a 'what is it like to be that'. In some ways, I see it as similar to asking what the temperature of a single electron is. The question simply doesn't make sense in that context.