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Benjamin son of Jacob; Amram father of Moshe; Yishai (Jesse) father of David and Kilav son of David.
This is recorded in the Talmud in Tractate Shabbat 55b3
Four people died due to Adam’s sin with the serpent, in the wake of which death was decreed upon all of mankind, although they themselves were free of sin. And they are: Benjamin, son of Jacob; Amram, father of Moses; Yishai, father of David; and Kilab, son of David.
Enoch may also have been without sin.